Search results for "Empirical equations"
showing 6 items of 6 documents
Kinetische untersuchungen zur strahleninduzierten festkörperpolymerisation von trioxan und tetroxan IV. Mitt. der Reihe “kinetische und morphologisch…
1971
Die strahlungsinduzierte Polymerisation von kristallinem Tetroxan und Trioxan wurde untersucht und der Einflus von Strahlendosis, Reaktionszeit und -temperatur auf den Umsatz und das Molekulargewicht der entstehenden POM, insbesondere bei der Nachpolymerisation, studiert. Die Zeit-Umsatz-Kurven fur die Nachpolymerisation laufen bei beiden Monomeren asymptotisch gegen einem Grenzwert des Umsatzes, der mit steigender Reaktionstemperatur ansteigt. Die Aktivierungsenergie der Nachpolymerisation wurde zu 24 ± 2 kcal/Mol fur Tetroxan und zu 36–38 kcal/Mol fur Trioxan bestimmt. Die Zeit(t)-Umsatz(x)-Kurven fur Tetroxan lassen sich durch die empirische Gleichung: beschreiben, wobei k1 und k2 Konsta…
Effects of soil gas permeability and recirculation flux on soil CO2 flux measurements performed using a closed dynamic accumulation chamber
2009
Abstract Dynamic accumulation chamber methods have been extensively used to estimate the total output of CO2 released from active volcanic area. In order to asses the performance and reliability of a closed dynamic system several tests were carried out with different soil permeabilities and soil CO2 fluxes. A special device was used to create a constant one-dimensional CO2 flux through a soil column with a known permeability. Three permeabilities were investigated, ranging between 3.6 × 10− 2 and 3.5 × 10 μm2, as were several CO2 fluxes (ranging between 1.1 × 10− 6 and 6.3 × 10− 5 kg m− 2 s− 1). The results highlight that the accuracy of soil CO2 flux measurements strictly depends on the so…
Empirical relationships for monitoring water quality of lakes and reservoirs through multispectral images
2014
Remote sensing techniques can be used to estimate water quality variables such as chlorophyll ${\mbi a}$ , total suspended particles, and water transparency. This paper describes empirical algorithms for the estimation of these variables using Landsat Thematic Mapper (TM) data. Ground data were taken from several Spanish lakes covering a variety of trophic statuses, ranging from oligotrophic to hypereutrophic. The studied lakes were the Albufera de Valencia and lakes and ponds of the Southeast Regional Park in Madrid. Empirical equations were obtained to estimate chlorophyll ${\mbi a}$ from the ratio in reflectance values between bands 2 and 4 of TM ( $\bf{ R^2 \, {\mmb =}\, 0.66}$ , ${\bf …
Computation of flow velocity in rough channels
2006
Accurate estimate of flow-velocity profile is of crucial importance both for scientific purposes and for solving numerous engineering problems that include, among others, sediment transport, contaminant transport, flow resistance evaluation. This paper presents a new empirical equation to represent the vertical velocity profile. The proposed equation is essentially a modified form of the well-known logarithm law of the wall and contains three parameters having a clear physical meaning. The applicability of the equation and its accuracy assessment for different hydraulic conditions, including non-uniform conditions, is verified by using experimental data obtained by different sources. The va…
Strong etching formulation (time and rate) for PADC with deep depth bulk etch rate study
2021
Abstract Aqueous NaOH with ethanol (strong) etchant is widely used. It shortens etching time effectively compared to normal etching conditions (6.25N NaOH at 70 °C). Two equations have been proposed to calculate the etching time with NaOH molarity and ethanol volume. Another two empirical equations were introduced for estimating the bulk etch rates of PADC etched in strong etchant. Up to now, there were no such equations available in the literature that can predict etching time and V b of PADC with etchant molarity and ethanol volumes. The proposed equations were compared to fundamental V b models stemming from literature. Fast etching enables the follow-up of bulk etch rate variation versu…
Short-duration rainfalls in Sicily
1990
The Italian Hydrographic Service publishes yearly maximum rainfall depths with 1-, 3-, 6-, 12-, and 24-hr duration, recorded by recording rain gauges. It also publishes selected short-duration (t<1 hr) rainfall amounts. It is impossible to carry out a statistical analysis of the short-duration rainfalls for each recording rain gauge because the published data correspond to different record durations and to different recording rain gauges from year to year. Therefore, there is a practical need to derive empirical relationships between the 1-, 3-, 6-, 12-, and 24-hr duration amounts and shorter duration (t<1 hr) rainfall amounts. Such a relationship has been proposed by Bell and has been veri…